liviu at stanforddotedu   B.S. in Chemistry with Honors,  California Institute of Technology, 1999 Undergraduate Advisor: Prof. Harry B. Gray

Interests in the StackLab: Cu / O₂ chemistry.
 
 

Publications: (click on the number to get the pdf file)

(9) m-h²:h²-Peroxodicopper(II) Complex with a Secondary Diamine Ligand: A Functional Model of Tyrosinase
Mirica L. M., Rudd Jackson D., Vance M. A., Solomon E. I., Hodgson K. O., Hedman B., Stack T. D. P.
J. Am. Chem. Soc.2006, 128, 8, 2654-2665.

(8) Bis(m-oxo)dicopper(III) Complexes of a Homologous Series of Simple Peralkylated 1,2-Diamines: Steric Modulation of Structure, Stability, and Reactivity
Cole A.P, Mahadevan V., Mirica L.M., Ottenwaelder X., Stack T.D.P.
Inorg. Chem. 2005, 44, 21, 7345-7364.

(7) Variable-Temperature, Variable-Field Magnetic Circular Dichroism Studies of Tris-Hydroxy- and 3-Oxo-Bridged Trinuclear Cu(II) Complexes: Evaluation of Proposed Structures of the Native Intermediate of the Multicopper Oxidases
Yoon J., Mirica L.M., Stack T.D.P., Solomon E.I.
J. Am. Chem. Soc.2005, 127, 39, 13680-13693.

(6) Tyrosinase Reactivity in a Model Complex: An Alternative Hydroxylation Mechanism
Mirica L.M., Vance M., Jackson-Rudd D., Hedman B., Hodgson K.O., Solomon E.I., Stack T.D.P.
Science, 2005, 308, 5730, 1890-1892

(5) A Tris(m-hydroxy)tricopper(II) Complex as a Model of the Native Intermediate in Laccase and Its Relationship to a Binuclear Analogue
Mirica, L.M., Stack, T.D.P.
Inorg. Chem. 2005, 44, 7, 2131-2133.

(4) Snapshots of a Metamorphosing Cu(II) Ground State in a Galactose Oxidase-Inspired Complex
Pratt R.C., Mirica L.M., and Stack T.D.P.
Inorg. Chem. 2004, 43, 25, 8030-8039.

(3) Spectroscopic Demonstration of a Large Antisymmetric Exchange Contribution to the Spin-Frustrated Ground State of a D3 Symmetric Hydroxy-Bridged Trinuclear Cu(II) Complex: Ground-to-Excited State Superexchange Pathways
Yoon, J., Mirica, L. M., Stack, T. D. P., Solomon, E. I.
J. Am. Chem. Soc.2004, 126, 39, 12586-12595.

(2) Structure and Spectroscopy of Copper-Dioxygen Complexes
Mirica L.M., Ottenwaelder X., Stack T.D.P.
Chem. Rev. 2004, 104, 2, 1013-1045.

(1) A Stabilized m-h²:h² Peroxodicopper(II) Complex with a Secondary Diamine Ligand and Its Tyrosinase-like Reactivity
Mirica L.M., Vance M., Jackson-Rudd D., Hedman B., Hodgson K.O., Solomon E.I., Stack T.D.P.
J. Am. Chem. Soc. 2002, 124, 32, 9332-9333.