(100) High-Valent Copper in Biomimetic and Biological Oxidations
Keown, W.; Gary, J.B.; Stack, T.D.P. J. Biol. Inorg. Chem. 2016. DOI: 10.1007/s00775-016-1420-5

(99) Simplest Monodentate Imidazole Stabilization of the oxy-Tyrosinase Cu2O2 Core: Phenolate Hydroxylation through a CuIII Intermediate
Chiang, L.; Keown, W.; Citek, C.; Wasinger, E.C.; Stack, T.D.P. Angew. Chem. Int. Ed. 2016, 55, 10453-10457. DOI: 10.1002/anie.201605159

(98) Direct Copper(III) Formation from O2 and Copper(I) with Histamine Ligation
Gary, J.B.; Citek, C.; Brown, T.A.; Zare, R.N.; Wasinger, E.C.; Stack, T.D.P. J. Am. Chem. Soc. 2016, 138, 9986-9995. DOI: 10.1021/jacs.6b05538

(97) Manganese(II)/Picolinic Acid Catalyst System for Epoxidation of Olefins
Moretti, R.A.; Du Bois, J.; Stack, T.D.P. Org. Lett. 2016, 18, 2528-2531. DOI: 10.1021/acs.orglett.6b00518

(96) Metal Complex Assembly Controlled by Surface Ligand Distribution on Mesoporous Silica: Quantification Using Refractive Index Matching and Impact on Catalysis
Smith, B.J.; Gallegos, P.A.H.; KButsch, K.; Stack, T.D.P. J. Catal. 2016, 335, 197-203. DOI: 10.1016/j.jcat.2015.11.008

(95) Formation of Hybrid Guanidine-Stabilized Bis(µ-oxo)-Dicopper Cores in Solution: Electronic and Steric Perturbations
Herres-Pawlis, S.; Haase, R.; Verma, P.; Hoffmann, A.; Kang, P.; Stack, T.D.P. Eur. J. Inorg. Chem. 2015, 32, 5426-5436. DOI: 10.1002/ejic.201500884

(94) Low Temperature Syntheses and Reactivity of Cu2O2 Active-Site Models
Citek, C.; Herres-Pawlis, S.; Stack, T.D.P. Acc. Chem. Res. 2015, 48, 2424-2433. DOI: 10.1021/acs.accounts.5b00220

(93) Chemical Plausibility of Cu(III) with Biological Ligation in pMMO
Citek, C.; Gary, J.B.; Wasinger, E.C.; Stack, T.D.P. J. Am. Chem. Soc. 2015, 137, 6991-6994. DOI: 10.1021/jacs.5b02157

(92) Sequential "Click" Functionalization of Mesoporous Titania for Energy-Relay Dye Enhanced Dye-Sensitized Solar Cells
Unger, E.L.; Fretz, S.J.; Lim, B.; Margulis, G.Y.; McGehee, M.D.; Stack, T.D.P. Phys Chem Chem Phys 2015, 17, 6565-6571. DOI: 10.1039/C4CP04878D

(91) Primary Amine Stabilization of a Dicopper(III) Bis(µ-oxo) Species: Modeling the Ligation in pMMO
Citek, C; Lin, B; Phelps, T.E.; Wasinger, E.C.; Stack, T.D.P. J. Am. Chem. Soc. 2014, 136, 14405-14408. DOI: 10.1021/ja508630d

(90) Ligand Noninnocence of Thiolate/Disulfide in Dinuclear Copper Complexes: Solvent-Dependent Redox Isomerization and Proton-Coupled Electron Transfer
Thomas, A.M.; Lin, B; Wasinger, E.C.; Stack, T.D.P. J. Am. Chem. Soc. 2013, 135, 18912-18919. DOI: 10.1021/ja409603m

(89) Squish and CuAAC: Additive-Free Covalent Mono layers of Discrete Molecules in Seconds
Pellow, M.A.; Stack, T.D.P.; Chidsey, C.E.D. Langmuir 2013, 29, 5383-5387. DOI: 10.1021/la400172w

(88) Catalytic Phenol Hydroxylation with Dioxygen: Extension of the Tyrosinase Mechanism beyond the Protein Matrix
Hoffmann, A; Citek, C.T.; Binder, S; Goos, A; Rubhausen, M; Troeppner, O; Ivanovic-Burmazovic, I; Wasinger, E.C.; Stack, T.D.P.; Herres-Pawlis, S. Angew. Chem. Int. Ed. 2013, 52, 5398-5401. DOI: 10.1002/anie.201301249

(87) Gas-Phase Azide Functionalization of Carbon
Stenehjem, E.D.; Ziatdinov, V.R.; Stack, T.D.P.; Chidsey, C.E.D. J. Am. Chem. Soc. 2013, 135, 1110-1116. DOI: 10.1021/ja310410d

(86) Recent advances in phenoxyl radical complexes of salen-type ligands as mixed-valent galactose oxidase models
Lyons, C.T.; Stack, T.D.P. Coord. Chem. Rev. 2013, 257, 528-540. DOI: 10.1016/j.ccr.2012.06.003

(85) Electrochemical and spectroscopic effects of mixed substituents in bis(phenolate)-copper(II) galactose oxidase model complexes
Pratt, R.C.; Lyons, C.T.; Wasinger, E.C.; Stack, T.D.P. J. Am. Chem. Soc. 2012, 134, 7367-7377. DOI: 10.1021/ja211247f

(84) Self-assembly of the oxy-tyrosinase core and the fundamental components of phenolic hydroxylation
Citek, C; Lyons, C.T.; Wasinger, E.C.; Stack, T.D.P. Nat. Chem. 2012, 4, 317-322. DOI: 10.1038/nchem.1284

(83) Discrete Complexes Immobilized onto Click-SBA-15 Silica: Controllable Loadings and the Impact of Surface Coverage on Catalysis
Nakazawa, J; Smith, B.J.; Stack, T.D.P. J. Am. Chem. Soc. 2012, 134, 2750-2759. DOI: 10.1021/ja210400u

(82) Sulfanyl Stabilization of Copper-Bonded Phenoxyls in Model Complexes and Galactose Oxidase
Verma, P; Pratt, R.C.; Storr, T; Wasinger, E.C.; Stack, T.D.P. PNAS 2011, 108, 18600-18605. DOI: 10.1073/pnas.1109931108

(81) Structural Dynamics of a Catalytic Monolayer Probed by Ultrafast 2D IR Vibrational Echoes
Rosenfeld, D.E.; Gengeliczki, Z.; Smith, B.J.; Stack, T.D.P.; Fayer, M.D. Science 2011, 334, 634-639. DOI: 10.1126/science.1211350

(80) Deposition of dense siloxane monolayers from water and trimethoxyorganosilane vapor
Lowe, R.; Pellow, M.; Stack, T.D.P.; Chidsey, C.E.D. Langmuir 2011, 27, 9928-9935. DOI: 10.1021/la201333y

(79) Tale of a Twist: Magnetic and Optical Switching in Copper(II) Semiquinone Complexes
Verma, P; Weir, John; Mirica, L; Stack, T.D.P. Inorg. Chem. 2011, ASAP. DOI: 10.1021/ic200958g

(78) Electrocatalytic O2 Reduction by Covalently Immobilized Mononuclear Copper(I) Complexes: Evidence for a Binuclear Cu2O2 Intermediate
McCrory, CCL; Devadoss, A; Ottenwaelder, X; Lowe, RD; Stack, T.D.P.; Chidsey, C.E.D. J. Am. Chem. Soc. 2011, 133, 3696-3699. DOI: 10.1021/ja106338h

(77) Bis(µ-oxo) Dicopper(III) Species of the Simplest Peralkylated Diamine: Enhanced Reactivity toward Exogenous Substrates
Kang P, Bobyr E, Dustman J, Hodgson KO, Hedman B, Solomon EI, Stack T.D.P.
Inorg. Chem. 2010, 49, 11030-11038. DOI: 10.1021/ic101515g

(76) Unexpected C-carbene-X (X: I, Br, Cl) Reductive Elimination from N-Heterocyclic Carbene Copper Halide Complexes Under Oxidative Conditions
Lin BL, Kang P, Stack T.D.P. Organometallics 2010, 29, 3683-3685. DOI: 10.1021/om1005726

(75) Facile C-H Bond Cleavage via a Proton-Coupled Electron Transfer Involving a C-H center dot center dot center dot Cu-II Interaction
Ribas X, Calle C, Poater A, Casitas A, Gomez L, Xifra R, Parella T, Benet-Buchholz J, Schweiger A, Mitrikas G , Sola M, Llobet A, Stack T.D.P. J. Am. Chem. Soc. 2010, 132, 12299-12306. DOI: 10.1021/ja101599e

(74) Ligand Radical Localization in a Nonsymmetric One-Electron Oxidized Ni-II Bis-phenoxide Complex
Storr T, Verma P, Shimazaki Y, Wasinger E. C., Stack T.D.P. Chem. A Eur. J. 2010, 16, 8980-8983. DOI: 10.1002/chem.201001401

(73) Detailed Evaluation of the Geometric and Electronic Structures of One-Electron Oxidized Group 10 (Ni, Pd, and Pt) Metal(II)-(Disalicylidene)diamine Complexes.
Shimazaki, Y.; Stack, T. D. P.; Storr, T. Inorg. Chem. 2009, 48, 8383-8392. DOI: 10.1021/ic901003q

(72) Reaction Coordinate of a Functional Model of Tyrosinase: Spectroscopic and Computational Characterization.
Holt, B. T. O.; Vance, M. A.; Mirica, L. M.; Heppner, D. E.; Stack, T. D. P.; Solomon, E. I. J. Am. Chem. Soc. 2009, 131, 6421-6438. DOI: 10.1021/ja807898h

(71) Phenolate Hydroxylation in a Bis(µ-oxo)dicopper(III) Complex: Lessons from the Guanidine/Amine Series.
Herres-Pawlis, S.; Verma, P.; Haase, R.; Kang, P.; Lyons, C. T.; Wasinger, E. C.; Florke, U.; Henkel, G.; Stack, T. D. P. J. Am. Chem. Soc. 2009, 131, 1154-1169. DOI: 10.1021/ja807809x

(70) Covalent heterogenization of a discrete Mn(II) bis-phen complex by a metal-template/metal-exchange method: An epoxidation catalyst with enhanced reactivity.
Terry, T. J.; Stack, T. D. P. J. Am. Chem. Soc. 2008, 130, 4945-4953. DOI: 10.1021/ja074203

(69) Defining the Electronic and Geometric Structure of One-Electron Oxidized Copper-Bis-phenoxide Complexes.
Storr, T.; Verma, P.; Pratt, R. C.; Wasinger, E. C.; Shimazaki, Y.; Stack, T. D. P. J. Am. Chem. Soc. 2008, 130, 15448-15459. DOI: 10.1021/ja804339m

(68) Spectroscopic and density functional theory studies of the blue-copper site in M121SeM and C112SeC azurin: Cu-Se versus Cu-S bonding.
Sarangi, R.; Gorelsky, S. I.; Basumallick, L.; Hwang, H. J.; Pratt, R. C.; Stack, T. D. P.; Lu, Y.; Hodgson, K. O.; Hedman, B.; Solomon, E.I. J. Am. Chem. Soc. 2008, 130, 3866-3877. DOI: 10.1021/ja076495a

(67) Controlled Loadings in a Mesoporous Material: Click-on Silica.
Nakazawa, J.; Stack, T. D. P. J. Am. Chem. Soc. 2008, 130, 14360-14361. DOI: 10.1021/ja804237b

(66) Synthesis, characterization and copper chemistry of a non-symmetric phenanthroline ligand: 2-methyl-9-(3,5-dimethyl-N-pyrazolylmethyl)-1,10-phenanthroline.
Masood, M. A.; Storr, T.; Stack, T. D. P. Inorg. Chim. Acta 2008, 361, 1142. DOI: 10.1016/j.ica.2007.09.016

(65) Site isolation and epoxidation reactivity of a templated ferrous bis(phenanthroline) site in porous silica.
Terry, T. J.; Dubois, G.; Murphy, A.; Stack, T. D. P. Angew. Chem. Int. Ed. 2007, 46, 945-947. DOI: 10.1002/anie.200603423

(64) The geometric and electronic structure of a one-electron-oxidized nickel(II) bis(salicylidene)diamine complex.
Storr, T.; Wasinger, E. C.; Pratt, R. C.; Stack, T. D. P. Angew. Chem. Int. Ed. 2007, 46, 5198-5201. DOI: 10.1002/anie.200701194

(63) Kinetic and mechanistic studies of the electrocatalytic reduction of O2 to H2O with mononuclear Cu complexes of substituted 1,10-phenanthrolines.
McCrory, C. C. L.; Ottenwaelder, X.; Stack, T. D. P.; Chidsey, C. E. D. J. Phys. Chem. A 2007, 111, 12641-12650. DOI: 10.1021/jp076106z

(62) Reversible O-O bond cleavage in copper-dioxygen isomers: impact of anion basicity
Ottenwaelder, X.; Rudd, DJ; Corbett, MC; Hodgson, KO; Hedman, B; Stack, TDP J. Am. Chem. Soc. 2006, 128, 9268-9269. DOI: 10.1021/ja061132g

(61) Hydrogen Atom Abstraction by a Mononuclear Ferric Hydroxide Complex: Insights into the Reactivity of Lipoxygenase
Goldsmith, C. R.; Stack, T. D. P. Inorg. Chem. 2006, 45, 6048-6055. DOI: 10.1021/ic060621e

(60) Discovery and optimization of rapid manganese catalysts for the epoxidation of terminal olefins
Murphy, A., Stack, T.D.P. J. Mol. Catal., A 2006 251, 78-88. DOI: 10.1016/j.molcata.2006.01.042

(59) µ-η22-Peroxodicopper(II) Complex with a Secondary Diamine Ligand: A Functional Model of Tyrosinase
Mirica L. M., Rudd Jackson D., Vance M. A., Solomon E. I., Hodgson K. O., Hedman B., Stack T. D. P. J. Am. Chem. Soc. 2006, 128, 2654-2665. DOI: 10.1021/ja056740v

(58) Bis(µ-oxo)dicopper(III) Complexes of a Homologous Series of Simple Peralkylated 1,2-Diamines: Steric Modulation of Structure, Stability, and Reactivity
Cole A.P, Mahadevan V., Mirica L.M., Ottenwaelder X., Stack T.D.P. Inorg. Chem. 2005, 44, 7345-7364. DOI: 10.1021/ic050331i

(57) Variable-Temperature, Variable-Field Magnetic Circular Dichroism Studies of Tris-Hydroxy- and µ(3)-Oxo-Bridged Trinuclear Cu(II) Complexes: Evaluation of Proposed Structures of the Native Intermediate of the Multicopper Oxidases
Yoon J., Mirica L.M., Stack T.D.P., Solomon E.I. J. Am. Chem. Soc. 2005, 127, 13680-13693. DOI: 10.1021/ja0525152

(56) Fine-Tuning the Electronic Properties of Highly Stable Organometallic Cu(III) Complexes Containing Monoanionic Macrocyclic Ligands
Xifra R., Ribas X., Llobet A., Poater A., Duran M., Sol M., Stack T.D.P., Benet-Buchholz J., Donnadieu B., Mahia J., Parella T. Chem. Eur. J. 2005, 11, 5146-5156. DOI: 10.1002/chem.200500088

(55) C-H Activation by a Mononuclear Manganese(III) Hydroxide Complex: Synthesis and Characterization of a Manganese-Lipoxygenase Mimic?
Goldsmith C.R., Cole A.P., Stack T.D.P. J. Am. Chem. Soc. 2005, 127, 9904-9912. DOI: 10.1021/ja039283w

(54) Tyrosinase Reactivity in a Model Complex: An Alternative Hydroxylation Mechanism
Mirica L.M., Vance M., Jackson-Rudd D., Hedman B., Hodgson K.O., Solomon E.I., Stack T.D.P. Science, 2005, 308, 1890-1892. DOI: 10.1126/science.1112081

(53) A Tris(µ-hydroxy)tricopper(II) Complex as a Model of the Native Intermediate in Laccase and Its Relationship to a Binuclear Analogue
Mirica, L.M., Stack, T.D.P. Inorg. Chem. 2005, 44, 2131-2133. DOI: 10.1021/ic048182b

(52) Mechanistic Insights from Reactions between Copper(II)-Phenoxyl Complexes and Substrates with Activated C-H Bonds
Pratt R.C., Stack T.D.P. Inorg. Chem. 2005, 44, 2367-2375. DOI: 10.1021/ic048695i

(51) X-ray Absorption Spectroscopic Investigation of the Spin-Transition Character in a Series of Single-Site Perturbed Iron(II) Complexes
Jackson Rudd D., Goldsmith C.R., Cole A.P., Stack T.D.P., Hodgson K.O., Hedman B. Inorg. Chem. 2005, 44, 1221-1229. DOI: 10.1021/ic048765l

(50) Snapshots of a Metamorphosing Cu(II) Ground State in a Galactose Oxidase-Inspired Complex
Pratt R.C., Mirica L.M., Stack T.D.P. Inorg. Chem. 2004, 43, 8030-8039. DOI: 10.1021/ic048904z

(49) Spectroscopic Demonstration of a Large Antisymmetric Exchange Contribution to the Spin-Frustrated Ground State of a D3 Symmetric Hydroxy-Bridged Trinuclear Cu(II) Complex: Ground-to-Excited State Superexchange Pathways
Yoon, J., Mirica, L.M., Stack T.D.P., Solomon E.I. J. Am. Chem. Soc. 2004, 126, 12586-12595. DOI: 10.1021/ja046380w

(48) Ligand and pH influence on manganese-mediated peracetic acid epoxidation of terminal olefins
Murphy A.J., Pace A., Stack T.D.P. Org. Lett. 2004, 6, 3119-3122. DOI: 10.1021/ol048846l

(47) Structure and spectroscopy of copper-dioxygen complexes
Mirica L.M., Ottenwaelder X., Stack T.D.P. Chem. Rev. 2004, 104, 1013-1045. DOI: 10.1021/cr020632z

(46) Intramolecular charge transfer and biomimetic reaction kinetics in galactose oxidase model complexes
Pratt R.C., Stack T.D.P. J. Am. Chem. Soc. 2003, 125, 8716-8717. DOI: 10.1021/ja035837j

(45) Simple iron catalyst for terminal alkene epoxidation
Dubois G., Murphy A.J., Stack T.D.P. Org. Lett. 2003, 5, 2469-2472. DOI: 10.1021/ol0347085

(44) Complexity with simplicity: a steric continuum of chelating diamines with copper(I) and dioxygen
Stack T.D.P. Dalton Trans. 2003, 1881-1889. DOI: 10.1039/b300201m

(43) Efficient epoxidation of electron-deficient olefins with a cationic manganese complex
Murphy A.J., Dubois G., Stack T.D.P. J. Am. Chem. Soc. 2003, 125, 5250-5251. DOI: 10.1021/ja029962r

(42) Oxidatively robust monophenolate-copper(II) complexes as potential models of galactose oxidase
Klein Gebbink R.J.M, Watanabe M., Pratt R.C. Stack T.D.P. Chem. Commun. 2003, 630-631. DOI: 10.1039/b212921c

(41) The EPR spectrum of a Cu(II/II/III) cluster: anisotropic exchange in a bent Cu(II)2O2 core
Machonkin T.E., Mukherjee P., Henson M.J.; Stack T.D.P., Solomon E.I. Inorg. Chim. Acta 2002, 341, 39-44. DOI: 10.1016/S0020-1693(02)01179-9

(40) A periodic walk: A series of first-row transition metal complexes with the pentadentate ligand PY5
Klein-Gebbink R.J.M., Jonas R.T., Goldsmith C.R., Stack T.D.P. Inorg. Chem. 2002, 41, 4633-4641. DOI: 10.1021/ic025617r

(39) A spectrochemical walk: Single-site perturbation within a series of six-coordinate ferrous complexes
Goldsmith C.R., Jonas R.T., Cole A.P., Stack T.D.P. Inorg. Chem. 2002, 41, 4642-4652. DOI: 10.1021/ic025616z

(38) Aryl C-H activation by CuII to form an organometallic Aryl-CuIII species: A novel twist on copper disproportionation
Ribas X., Jackson D.A., Donnadieu B., Mahia J., Parella T., Xifra R., Hedman B., Hodgson K.O., Llobet A., Stack T.D.P. Angew. Chem., Int. Ed. 2002, 41, 2991-2994. DOI: 10.1002/1521-3773(20020816)41:16<2991::AID-ANIE2991>3.0.CO;2-6

(37) A stabilized µ-η22 peroxodicopper(II) complex with a secondary diamine ligand and its tyrosinase-like reactivity
Mirica L.M., Vance M., Jackson-Rudd D., Hedman B., Hodgson K.O., Solomon E.I., Stack T.D.P. J. Am. Chem. Soc. 2002, 124, 9332-9333. DOI: 10.1021/ja026905p

(36) C-H bond activation by a ferric methoxide complex: Modeling the rate-determining step in the mechanism of lipoxygenase
Goldsmith C.R., Jonas R.T., Stack T.D.P. J. Am. Chem. Soc. 2002, 124, 83-96. DOI: 10.1021/ja016451g

(35) A new Cu(II) side-on peroxo model clarifies the assignment of the oxyhemocyanin Raman spectrum
Henson M.J., Mahadevan V., Stack T.D.P., Solomon E.I. Inorg. Chem. 2001, 40, 5068-5069. DOI: 10.1021/ic015539

(34) Differential reactivity between interconvertible side-on peroxo and bis-µ-oxodicopper isomers using peralkylated diamine ligands
Mahadevan V., Henson M.J., Solomon E.I., Stack T.D.P. J. Am. Chem. Soc. 2000, 122, 10249-10250. DOI: 10.1021/ja002527h

(33) Biomimetic modeling of copper oxidase reactivity
Mahadevan V., Gebbink R., Stack T.D.P.
Curr. Opin. Chem. Biol. 2000, 4, 228-234. DOI: 10.1016/S1367-5931(99)00080-0

(32) A systematic K-edge X-ray absorption spectroscopic study of Cu(III) sites
Dubois J.L., Mukherjee P., Stack T.D.P., Hedman B., Solomon E.I., Hodgson K.O.
J. Am. Chem. Soc. 2000, 122, 5775-5787. DOI: 10.1021/ja993134p

(31) Capturing the essence of a metalloenzyme.
Wang Y., Gebbink R., Dubois J., Hedman B., Hodgson K., Stack T.D.P.
J. Inorg. Biochem. 1999, 74, 52.

(30) Spectroscopic and electronic structural studies of the Cu(III)2 bis-µ-oxo core and its relation to the side-on peroxo-bridged dimer
Henson M.J., Mukherjee P., Root D.E., Stack T.D.P., Solomon E.I.
J. Am. Chem. Soc. 1999, 121, 10332-10345. DOI: 10.1021/ja9918425

(29) Exogenous Substrate Reactivity with a [Cu(III)2O2]2+: Core: Structural Implications
Mahadevan V., DuBois J.L., Hedman B., Hodgson K.O., Stack T.D.P.
J. Am. Chem. Soc. 1999, 121, 5583-5584. DOI: 10.1021/ja983635v

(28) Biomimetic catalysts for the oxidation of alcohols to carbonyl compounds by O2
Gebbink R., Stack, T.D.P.
J. Inorg. Biochem. 1999, 74, 138.

(27) Synthesis and characterization of a family of systematically varied tris(2-pyridyl)methoxymethane ligands: Copper(I) and copper(II) complexes
Jonas R.T., Stack T.D.P.
Inorg. Chem. 1998, 37, 6615-6629. DOI: 10.1021/ic9713487

(26) Electronic and geometric structure of a trinuclear mixed-valence copper(II,II,III) cluster
Root D.E., Henson M.J., Machonkin T., Mukherjee P., Stack T.D.P., Solomon E.I.
J. Am. Chem. Soc. 1998, 120, 4982-4990. DOI: 10.1021/ja973545a

(25) Stereospecificity and self-selectivity in the generation of a chiral molecular tetrahedron by metal-assisted self-assembly
Enemark E.J., Stack T.D.P.
Angew. Chem., Int. Ed. 1998, 37, 932-935. DOI: 10.1002/(SICI)1521-3773(19980420)37:7<932::AID-ANIE932>3.0.CO;2-C

(24) Ligand self-recognition in the self-assembly of a [{Cu(L)}2]2+ complex: The role of chirality
Masood M.A., Enemark E.J., Stack T.D.P.
Angew. Chem., Int. Ed. 1998, 37, 928-932. DOI: 10.1002/(SICI)1521-3773(19980420)37:7<928::AID-ANIE928>3.0.CO;2-T

(23) Catalytic galactose oxidase models: Biomimetic Cu(II)-phenoxyl-radical reactivity
Wang Y.D., Dubois J.L., Hedman B., Hodgson K.O., Stack T.D.P.
Science 1998, 279, 537-540. DOI: 10.1126/science.279.5350.537

(22) Irreversible reduction of dioxygen by simple peralkylated diamine-copper(I) complexes: Characterization and thermal stability of a [Cu2(µ-O)2]2+ core
Mahadevan V., Hou Z.G., Cole A.P., Root D.E., Lal T.K., Solomon E.I., Stack T.D.P.
J. Am. Chem. Soc. 1997, 119, 11996-11997. DOI: 10.1021/ja972946n

(21) Enhanced iron(III) chelation through ligand predisposition: syntheses, structures and stability of tris-catecholate enterobactin analogs
Hou Z.G., Stack T.D.P., Sunderland C.J., Raymond K.N.
Inorg. Chim. Acta 1997, 263, 341-355. DOI: 10.1016/S0020-1693(97)05664-8

(20) Cu K-edge XAS study of the [Cu2(µ-O)2] core: Direct experimental evidence for the presence of Cu(III)
Dubois J.L., Mukherjee P., Collier A.M., Mayer J.M., Solomon E.I., Hedman B., Stack T.D.P., Hodgson K.O.
J. Am. Chem. Soc. 1997, 119, 8578-8579. DOI: 10.1021/ja9717673

(19) C-H bond activation by a ferric methoxide complex: A model for the rate-determining step in the mechanism of lipoxygenase
Jonas R.T., Stack T.D.P.
J. Am. Chem. Soc. 1997, 119, 8566-8567. DOI: 10.1021/ja971503g

(18) Galactose oxidase model complexes: Catalytic reactivities
Wang Y.D., Stack T.D.P.
J. Am. Chem. Soc. 1996, 118, 13097-13098. DOI: 10.1021/ja9621354

(17) Spectral and structural characterization of two ferric coordination modes of a simple bis(catecholamide) ligand: Metal-assisted self-assembly in a siderophore analog
Enemark E.J., Stack T.D.P.
Inorg. Chem. 1996, 35, 2719-2720. DOI: 10.1021/ic960022f

(16) Trinuclear intermediate in the copper-mediated reduction of O2: Four electrons from three coppers
Cole A.P., Root D.E., Mukherjee P., Solomon E.I., Stack T.D.P.
Science 1996, 273, 1848-1850. DOI: 10.1126/science.273.5283.1848

(15) Theoretical and Experimental Studies of the Diels-Alder Dimerizations of Substituted Cyclopentadienes
Froese R.D.J., Organ M.G., Goddard J.D., Stack T.D.P., Trost B.M.
J. Am. Chem. Soc. 1995, 117, 10931-10938. DOI: 10.1021/ja00149a016

(14) Synthesis and Structural Characterization of a Stereospecific Dinuclear Gallium Triple-Helix: Use of the Transinfluence in Metal-Assisted self-Assembly
Enemark E.J., Stack T.D.P.
Angew. Chem., Int. Ed. 1995, 34, 996-998. DOI: 10.1002/anie.199509961

(13) Rational Reduction of the Conformational Space of a Siderophore Analog through Nonbonded Interactions: The Role of Entropy in Enterobactin
Stack T.D.P., Hou Z.G., Raymond K.N.
J. Am. Chem. Soc.1993, 115, 6466-6467. DOI: 10.1021/ja00067a094

(12) Stereoselectivity in Chiral Fe(III) and Ga(III) Tris(Catecholate) Complexes Effected by Nonbonded, Weakly Polar Interactions
Karpishin, T. B.; Stack, T. D. P.; Raymond, K. N.,
J. Am. Chem. Soc. 1993, 115, 6115. DOI: 10.1021/ja00067a029

(11) Octahedral Vs Trigonal Prismatic Geometry in a Series of Catechol Macrobicyclic Ligand Metal-Complexes
Karpishin T.B., Stack T.D.P., Raymond K.N.
J. Am. Chem. Soc. 1993, 115, 182-192. DOI: 10.1021/ja00054a025

(10) An 8-Coordinate Cage: Synthesis and Structure of the 1st Macrotricyclic Tetraterephthalamide Ligand
Xu J., Stack T.D.P., Raymond K.N.
Inorg. Chem. 1992, 31, 4903-4905. DOI: 10.1021/ic00050a001

(9) Structural and Spectroscopic Characterization of Chiral Ferric Tris-Catecholamides: Unraveling the Design of Enterobactin
Stack T.D.P., Karpishin T.B., Raymond K.N.
J. Am. Chem. Soc. 1992, 114, 1512-1514. DOI: 10.1021/ja00030a075

(8) The Cavitand Concept in the Synthesis of Subsite-Differentiated Analogs of Biological [4Fe-4S/Se]2+ Clusters: Cluster Capture Reactions, Ligand Conformational-Analysis, and the Structure of a Trigonal [4Fe-4Se]2+ Analog
Stack T.D.P., Weigel J.A., Holm R.H.
Inorg. Chem. 1990, 29, 3745-3760. DOI: 10.1021/ic00344a022

(7) Subsite-Differentiated Analogs of Native [4Fe-4S]2+ Clusters: Preparation of Clusters with 5-Coordinate and 6-Coordinate Subsites and Modulation of Redox Potentials and Charge-Distributions
Ciurli S., Carrie M., Weigel J.A., Carney M.J., Stack T.D.P., Papaefthymiou G.C., Holm R.H.
J. Am. Chem. Soc. 1990, 112, 2654-2664. DOI: 10.1021/ja00163a028

(6) Formation of Bridged [4Fe-4S]2+ Double Cubanes by Site-Specific Reactions: Electron-Transfer Coupling across Sulfur-Containing Bridges of Variable Length
Stack T.D.P., Carney M.J., Holm R.H.
J. Am. Chem. Soc. 1989, 111, 1670-1676. DOI: 10.1021/ja00187a020

(5) A New Class of (N,N'-Bis(Salicylideneamino)Ethanato)Iron(II) Complexes: 5-Coordinate [FeII(Salen)L]: Preparation, Properties, and Mechanism of Electron-Transfer Reactions
Mukherjee R.N., Abrahamson A.J., Patterson G.S., Stack T.D.P., Holm R.H.
Inorg. Chem. 1988, 27, 2137-2144. DOI: 10.1021/ic00285a026

(4) Angle Dependence of the Properties of the [Fe2O]4x, [Fe2S]4+ Bridge Unit: Structures, Antiferromagnetic Coupling, and Properties in Solution
Mukherjee R.N., Stack T.D.P., Holm R.H.
J. Am. Chem. Soc. 1988, 110, 1850-1861. DOI: 10.1021/ja00214a030

(3) Subsite-Differentiated Analogs of Biological [4Fe-4S]2+ Clusters: Synthesis, Solution and Solid-State Structures, and Subsite-Specific Reactions
Stack T.D.P., Holm R.H.
J. Am. Chem. Soc. 1988, 110, 2484-2494. DOI: 10.1021/ja00216a023

(2) Subsite-Specific Functionalization of the [4Fe-4S]2+ Analog of Iron Sulfur Protein Clusters
Stack T.D.P., Holm R.H.
J. Am. Chem. Soc. 1987, 109, 2546-2547. DOI: 10.1021/ja00242a067

(1) Synthesis, Structure, and Electronic Features of (µ-Sulfido)Bis[(N,N'-Ethylenebis(Salicylaldiminato))Iron(III)], [Fe(Salen)]2S, Containing the Only Authenticated Example ofthe Fe(III)-S-Fe(III) Single Bridge
Dorfman J.R., Girerd J.J., Simhon E.D., Stack T.D.P., Holm R.H.
Inorg. Chem. 1984, 23, 4407-4412. DOI: 10.1021/ic00194a002